It is used to synthesize organofluorine compounds. The lethal minimum dose (guinea pig, oral) is 100 mg/kg. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. It is synthesized by treatment of antimony trichloride and methyl Grignard reagent. "c" indicates that although not listed by name and CAS number, this chemical is reportable under one or more of the EPCRA section 313 chemical categories. Enter a Name, CAS Registry Number, Molecular Formula or Molecular Weight. Molecular Weight: 178.76 Molecular Formula: F3Sb Additional Metadata. Antimony trichloride is the chemical compound with the formula SbCl3. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. As well as some industrial applications, [2] it is used as a reagent in inorganic and organofluorine chemistry. Formula and structure: The antimony pentafluoride chemical formula is SbF 5 and its molar mass is 216.74 g mol -1. Antimony(III) Fluoride is a water insoluble Antimony source for use in oxygen-sensitive applications, such as metal production. Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. Edited by G. Brauer, Academic Press, 1963, NY. View the Full Spectrum for FREE! Antimony trifluoride EC Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. The SI base unit for amount of substance is the mole. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds, some of which are important in the pharmaceutical and specialty chemical industries. & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. Antimony(III) oxide is the inorganic compound with the formula Sb2O3. Arsenic pentoxide is the inorganic compound with the formula As2O5. It has antimony and fluoride ions in … including trade names and synonyms. Hydrates are also known. In addition to these applications, some organofluorine compounds are pollutants because of their contributions to ozone depletion, global warming, bioaccumulation, and toxicity. antimony trifluoride. 1 mole is equal to 1 moles Antimony Trifluoride, or 178.7552096 grams. The molecular formula for Antimony Trifluoride is SbF3. Belongs to the Following Reactive Group(s), Approved respirator, rubber gloves. It appears as a white solid. Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. (USCG, 1999). It is the most important source for the metalloid antimony. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. National Oceanic and Atmospheric Administration. The id formed by a central cation of antimonium Sb +5 and 5 fluoride anions F -. 5g; Plastic bottle. Formula: SbCl 3 Hill system formula: Cl 3 Sb 1 CAS registry number: [10025-91-9] Formula weight: 228.118 Class: chloride Colour: white Appearance: crystalline solid, deliquescent Melting point: 73.4°C Boiling point: 223°C Density: 3140 kg m-3 National Institute for Occupational Safety and Health. Antimony trifluoride is the inorganic compound with the formula SbF3. Because it is a polymer, SbF3 is far less volatile than related compounds AsF3 and SbCl3. (USCG, 1999), If any symptoms, however slight, are noticed, the affected individual should be removed from contact with the chemical and placed under the care of a physician who is versed in the treatment necessary. It is the most important commercial compound of antimony. ... Antimony trifluoride Antimony tribromide Antimony triiodide: Other cations. In solid SbF3, the Sb centres have octahedral molecular geometry and are linked by bridging fluoride ligands. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities. Water slowly hydrolyzes antimony fluoride to form antimony (III) oxide. Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. Vinyl fluoride is an organic halide with the chemical formula C2H3F. For many elements the highest known oxidation state can be achieved in a fluoride. It reacts with water to make antimony trioxide and hydrochloric acid or hydrogen chloride.. It is a colorless gas with a faint etherlike odor. This white solid, discovered by José Bonifácio de Andrada e Silva, occurs naturally as the mineral cryolite and is used extensively in the industrial production of aluminium metal. The full spectrum can only be viewed using a FREE account. Note that rounding errors may occur, so always check the results. The anhydrous compound is a hygroscopic brown solid. Sodium aluminium hexafluoride is an inorganic compound with formula Na3AlF6. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. Antimony trifluoride is the inorganic compound with the formula SbF3. It can also be prepared by allowing fluorine to react with antimony powder or molten antimony trifluoride. The SI base unit for amount of substance is the mole. As the fluorinated derivative of butyric acid, this colourless liquid is prepared by electrofluorination of the corresponding butyryl fluoride. nH 2 O. A colorless, solid compound, toxic and corrosive. 0 - 100 (6) 101 - 200 (2) 201 - 300 (3) Boiling Point (°C) 0 - 100 (1) 101 - 200 (4) Melting Point (°C) 0 - 100 (5) 201 - 300 (1) ... Antimony trifluoride, Trifluorostibine Linear Formula: SbF 3. Antimony trifluoride. The antimony pentafluoride is separated from the volatile byproducts by fractional distillation. It has a strong odor and absorbs water from the air. It appears as a white solid. with oxygen as well as other oxidants. This poisonous oil is colourless, although impure samples may appear yellow. Antimony trichloride is the chemical compound with the formula SbCl 3. Antimony trifluoride,CAS,7783-56-4,Antimony trifluoride suppliers ChemWhat provides identification, property, safety and original manufacturer information for Antimony trifluoride CAS#: 7783-56 … Molecules containing fluorine may also exhibit hydrogen bonding. This soft grey material crystallizes in an orthorhombic space group. It is used as a fluorination reagent in organic chemistry. Organofluorine chemistry describes the chemistry of the organofluorines, organic compounds that contain the carbon–fluorine bond. More common, and far more important commercially, is arsenic(III) oxide (As2O3). The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony.Antimony trichloride is … It is a colorless liquid which reacts readily with water. It is produced by anaerobic bacteria in antimony-rich soils. They are mainly of interest by researchers, unlike the related iron(III) chlorides. Formula Weight. Other fluorine-containing Lewis acids serve as fluorinating agents in conjunction with hydrogen fluoride. The dry powdered oxide ignites on heating in air [Mellor Vol. This pungent colourless toxic gas forms white fumes in moist air. Uses. The compound is a mild Lewis acid, hydrolyzing slowly in water. National Ocean Service, Hydrogen fluoride is a chemical compound with the chemical formula HF. Use caution: Liquids with this reactive group classification have been USA.gov. Except where otherwise noted, data are given for materials in their. The compound is the sodium (Na+) salt of the hexafluoroaluminate (AlF63−) ion. Web site owner: Antimony trifluoride EC Inventory, C&L Inventory, REACH pre-registration, CAD - Chemical Agents Directive, Art. It is a colorless gas. 1. p. 199. Synonyms: Antimony trifluoride CAS #: 7783-56-4 EC Number: 232-009-2 Molar Mass: 178.74 g/mol Hill Formula: F₃Sb Chemical Formula: SbF₃ 807839 It is an intermediate in the manufacture of organoarsenic compounds. It is made by reacting chlorine with antimony, antimony trioxide, or antimony trisulfide.. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink. Vol. Fluoride may act as a bridging ligand between two metals in some complex molecules. Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. These regulations apply to discharges of this substance. Preparation. It is a corrosive species that releases dangerous HF upon exposure to water or moisture. Antimony trifluoride, also known as antimony (III) fluoride or Swart's reagent, is a chemical compound. This colourless, viscous liquid is a valuable Lewis acid and a component of the superacid fluoroantimonic acid, the strongest known acid, formed when mixing liquid HF with liquid SbF5 in a 2:1 ratio. Formula: SbF 3; Hill system formula: F 3 Sb 1; CAS registry number: [7783-56-4] Formula weight: 178.755; Class: fluoride Colour: colourless; Appearance: crystalline solid; Melting point: 290°C; Boiling point: 345°C; Density: 4380 kg m-3 Sulfur tetrafluoride is the chemical compound with the formula SF4. Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. This colourless gas is the epoxide of hexafluoropropylene, that is fluorinated analog of propylene oxide, HFPO is produced by DuPont and 3M and as a precursor to the lubricant Krytox and related materials. Hydrogen fluoride boils near room temperature, much higher than other hydrogen halides. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. HF is widely used in the petrochemical industry as a component of superacids. This compound can also be produced in bulk. 7783-56-4 - GUNJVIDCYZYFGV-UHFFFAOYSA-K - Antimony trifluoride - Similar structures search, synonyms, formulas, resource links, and other chemical information. The geometry of the molecule is a trigonal bipyramide, with a base formed by 3 bonds Sb-F and two axial bonds, which form the vertices. It is used in the production of some III-V semiconductors. Handbook of Preparative Inorganic Chemistry, 2nd Ed. It is a white insoluble solid. known to react with the Properties. It contains antimony in the +5 oxidation state. Antimony trifluoride is the inorganic compound with the formula SbF3. Antimony trifluoride is the inorganic compound with the formula SbF … Antimony trifluoride is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. See 50 Federal Register 13456 (April 4, 1985). The liquid contains polymers wherein each Sb is octahedral, the structure being described with the formula [SbF4(μ-F)2]n ((μ-F) denotes the fact that fluoride centres bridgetwo Sb centres). More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. The molecular formula for Antimony Trifluoride is SbF3. Boron trifluoride is the inorganic compound with the formula BF3. [5] This application was reported by the Belgian chemist Frédéric Jean Edmond Swarts in 1892, [6] who demonstrated its usefulness for converting chloride compounds to fluorides. All arsenic compounds are highly toxic and thus find only limited commercial applications. Freon, a very useful refrigerant, is produced in the following reaction: 3CCl4 (g) + 2SbF3 (s) → 3CCl2F2 (g) + 2SbCl3 (s) (Freon) Suppose a chemist wanted to make 115.0 liters of Freon using excess antimony … In the gas phase, SbF5 adopts a trigonal bipyramidal structure of D3h point group symmetry (see picture). It is used in ceramics and to make other chemicals. A monofluoride is a chemical compound with one fluoride per formula unit. Its chemical formula is SbF 3. Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. It is used to detect Vitamin A.It is used to get horns off calves. 1 grams Antimony Trifluoride is equal to 0.005594242552358 mole. [3], SbF3 is prepared by treating antimony trioxide with hydrogen fluoride: [4]. Fluoride compounds have diverse applications in current technologies and science, from oil refining and etching to synthetic organic chemistry and the manufacture of pharmaceuticals. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others the highest oxidation states of oxides and fluorides are always equal. Antimony pentafluoride is prepared by treating antimony pentachloride with excess anhydrous hydrogen fluoride. Antimony trichloride is a white or pale yellow solid. Antimony Compounds: N010 & 313: Antimony trifluoride: 7783-56-4: 1000 pounds: 313c It is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers. As well as some industrial applications, it is used as a reagent in inorganic and organofluorine chemistry. This colorless gas or liquid is the principal industrial source of fluorine, often as an aqueous solution called hydrofluoric acid. Organofluorine compounds find diverse applications ranging from oil and water repellents to pharmaceuticals, refrigerants, and reagents in catalysis. The name is from the Greek στίβι stibi through the Latin stibium as the old name for the mineral and the element antimony. Antimony trifluoride. For a binary compound, this is the formula XF. CHRONIC POISONING: dryness of throat; pain on swallowing; occasional vomiting and persistent nausea; susceptibility to fainting; diarrhea, loss of appetite and weight; giddiness; dermatitis, either pustular or ulcerative; anemia (USCG, 1999). As well as some industrial applications, it is used as a reagent in inorganic and organofluorine c The material adopts a more complicated structure in the liquid and solid states. It is notable for its Lewis acidity and its ability to react with almost all known compounds. Formula: F 3 Sb; Molecular weight: 178.755; CAS Registry Number: 7783-56-4; Information on this page: Notes; Other data available: Phase change data; Gas phase ion energetics data; Data at other public NIST sites: X-ray Photoelectron Spectroscopy Database, version 4.1; Options: Switch to calorie-based units 9 425.1939]. It is a useful Lewis acid and a versatile building block for other boron compounds. Cobalt(III) fluoride is the inorganic compound with the formula CoF3. It is used as the monomeric precursor to the fluoropolymer polyvinylfluoride. It is generated by oxidation of perfluoropropylene, e.g. It is corrosive to tissue. This section provides a listing of alternate names for this chemical, Molecular Weight: 178.76 Molecular Formula: F3Sb Additional Metadata. With fluorine, it is oxidized to give antimony pentafluoride. Heptafluorobutyric acid (HFBA) is an organofluorine compound with the formula C3F7CO2H. Office of Response and Restoration, The method involved treatment with antimony trifluoride with chlorine or with antimony pentachloride to give the active species antimony trifluorodichloride (SbCl2F3). listed below. The area of organofluorine chemistry often requires special techniques associated with the handling of fluorinating agents. [9]. Note that rounding errors may occur, so always check the results. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. The crystalline material is a tetramer, meaning that it has the formula [SbF4(μ-F)]4. [8] It was once used for the industrial production of freon. It is a colorless pyrophoric and toxic liquid. ACUTE POISONING: irritation of the mouth, nose, stomach and intestines; vomiting, purging with bloody stools; slow pulse and low blood pressure; slow, shallow breathing; coma and convulsions sometimes followed by death from cardiac and respiratory exhaustion. The Sb-F bonds are 2.02 Å within the eight-membered Sb4… The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony. It is corrosive to tissue. [7] The Swarts reaction is generally applied to the synthesis of organofluorine compounds, but experiments have been performed using silanes. It is used in ceramics and to make other chemicals. Add a … absorbents It is found in nature as the minerals valentinite and senarmontite. Shop a large selection of Antimony products and learn more about Antimony trifluoride, 98%, ACROS Organics. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. Three Sb–F bonds are short (192 pm) and three are long (261 pm). SbF3 is used in dyeing and in pottery, to make ceramic enamels and glazes. It appears as a white solid. Antimony pentafluoride is the inorganic compound with the formula SbF5. When heated to decomposition, it emits very toxic fumes of fluoride and metallic antimony [Lewis, 3rd ed., 1993, p. 83]. Trimethylstibine is an organoantimony compound with the formula Sb(CH3)3. Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. Arsenic trichloride is an inorganic compound with the formula AsCl3, also known as arsenous chloride or butter of arsenic. Antimony trifluoride agent detailed information in Haz-Map database. Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf “Antimony and Antimony Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. 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